硫化铥是一种无机化合物,化学式为Tm2S3。它可由铥和硫在氯化钠熔体中于850 °C反应得到,[1]或氧化铥和硫化氢在1200~1300 °C的反应来制备。[2]
它和三氟化铥在高温反应,可以得到TmSF。[3]它和硫氧化铀(UOS)在高温反应,可以得到(UO)2TmS3。[4]
参考文献[编辑]
- ^ Thomas Schleid, Falk Lissner. Single crystals of F-Tm2S3 and T-Yb2S3. Journal of Alloys and Compounds. 1992-11, 189 (1): 69–74 [2023-04-05]. doi:10.1016/0925-8388(92)90048-E. (原始内容存档于2018-06-21) (英语).
- ^ Collin, G.; Loriers, J. Oxysulfides and sesquisulfides of terbium, holmium, thulium, and lutetium. Compt. Rend.. 1965. 260 (19). 5043-5046.
- ^ Zinchenko, V. F.; Efryushina, N. P.; Antonovich, V. P.; Eremin, O. G.; Stamikosto, O. V.; Kovalevskaya, I. P. Synthesis and optical properties of rare earth sulfofluorides. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2000. 66 (3-4): 16-19.
- ^ Guittard, M.; Vovan, T.; Julien-Pouzol, M.; Jaulmes, S.; Laruelle, P.; Flahaut, J. Description and structural study of a new family of sheet compounds of the general composition (UO)2RS3 (R = Gd to Lu and Y). Zeitschrift fuer Anorganische und Allgemeine Chemie, 1986. 540-541: 59-66.