In organic chemistry, TADDOL is an acronym for α,α,α',α'-tetraaryl-2,2-disubstituted 1,3-dioxolane-4,5-dimethanol. These compounds are easily accessed...

tartrate and titanium isopropoxide form a chiral catalyst in situ. The TADDOL ligand scaffold is produced from diethyl tartrate. Hill, J. Gordon; Sharpless...

Dieter; Beck, Albert K.; Heckel, Alexander (5 January 2001). "TADDOLs, Their Derivatives, and TADDOL Analogues: Versatile Chiral Auxiliaries". Angewandte Chemie...

Well known examples include cyclic diesters derived from the BINOL and TADDOL motifs. These compounds are used in asymmetric catalysis as chiral Brønsted...

transformation. An asymmetric version of this reaction is also known with a TADDOL-based catalyst. The generally accepted reaction mechanism initially utilizes...

BioMedicinal Chemistry 2004 The Ryoji Noyori Prize 2019 Arthur C. Cope Award TADDOL DMPU Chiral column chromatography Corey-Seebach reaction Hook, David F....

on α,α,α',α'-tetraaryl-2,2-disubstituted 1,3-dioxolane-4,5-dimethanol (TADDOL) that could catalyze Diels-Alder reactions. In the following example, the...

were synthesized from the natural product (+)-a-pinene in two steps. The TADDOL ligands developed by Dieter Seebach has been used to prepare chiral allyltitanium...

synthesis Both enantiomers of BINAP BINOL, another binaphthalene-based ligand TADDOL DIPAMP, a diphosphine of historic significance AD-mix α, dihydroquinine...

catalysts derived from biomolecules. Hydrogen bonding catalysts, including TADDOLS, derivatives of BINOL such as NOBIN, and organocatalysts based on thioureas...