In chemistry, dioxirane (systematically named dioxacyclopropane, also known as methylene peroxide or peroxymethane) is an organic compound with formula...
5 KB (446 words) - 09:42, 23 April 2024
Epoxidation with dioxiranes refers to the synthesis of epoxides from alkenes using three-membered cyclic peroxides, also known as dioxiranes. Dioxiranes are three-membered...
9 KB (1,240 words) - 14:29, 8 June 2024
Oxidation with dioxiranes refers to the introduction of oxygen into organic molecules through the action of a dioxirane. Dioxiranes are well known for...
11 KB (1,287 words) - 15:29, 1 February 2024
Dimethyldioxirane (category Dioxiranes)
(DMDO) is the organic compound with the formula (CH3)2CO2. It is the dioxirane derived from acetone and can be considered as a monomer of acetone peroxide...
5 KB (445 words) - 14:51, 11 April 2024
Shi epoxidation (section Dioxirane catalyst formation)
fructose-derived catalyst (1). This reaction is thought to proceed via a dioxirane intermediate, generated from the catalyst ketone by oxone (potassium peroxymonosulfate)...
10 KB (1,183 words) - 20:37, 22 July 2024
formula CH2O2 (molar mass: 46.03 g/mol) may refer to: Dihydroxymethylidene Dioxirane, an unstable cyclic peroxide Formic acid, an organic acid Methylenedioxy...
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symmetry point groups Cs, D3h, and C2v. The C2v state, consisting of a dioxirane, has been shown to be the ground state of the molecule. Carbon trioxide...
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Dimesityldioxirane (category Dioxiranes)
Dimesityldioxirane is a substituted dioxirane with two mesityl groups attached to the dioxirane carbon. It is a colorless crystalline substance stable...
4 KB (236 words) - 19:15, 2 August 2024
Difluorodioxirane (category Dioxiranes)
is a rare, stable member of the dioxirane family, known for a single oxygen-oxygen bond (O-O). Unlike most dioxiranes that decompose quickly, difluorodioxirane...
7 KB (552 words) - 17:09, 31 May 2024
without the intervention of metal catalysts. In specialized applications, dioxirane reagents (e.g. dimethyldioxirane) perform similarly, but are more explosive...
22 KB (2,324 words) - 21:50, 25 August 2024