Dihydrogen complexes are coordination complexes containing intact H2 as a ligand. They are a subset of sigma complexes. The prototypical complex is W(CO)3(PCy3)2(H2)...

bond. Dihydrogen complexes are examples. Transition metal silane complexes are often especially stable sigma complexes. A subset of sigma complexes are...

for the eight C−H bonds. Transition metal complexes that feature multiple bonds, such as the dihydrogen complex, have sigma bonds between the multiple bonded...

organometallic compound with the formula W(CO)6. This complex gave rise to the first example of a dihydrogen complex. Like its chromium and molybdenum analogs, this...

Hbase+ Such reaction are assumed to involve the intermediacy of dihydrogen complexes. Bifunctional catalysts activate H2 in this way. The values shift...

2-Norbornyl cation. Three-center four-electron bond 2-Norbornyl cation Dihydrogen complex I. Mayer (1989). "Bond orders in three-centre bonds: an analytical...

The compound has attracted much attention as a precursor to dihydrogen complexes. The complex exhibits octahedral molecular geometry. The chloride and hydride...

R3−nHnPBH3, are adducts of organophosphines and borane. Borane(5) is the dihydrogen complex of borane. Its molecular formula is BH5 or possibly BH3(η2-H2). It...

to give a dihydride complex via oxidative addition (preceding the oxidative addition of H2 is the formation of a dihydrogen complex): LnM + H2 → LnMH2...

The dihydrogen cation or hydrogen molecular ion is a cation (positive ion) with formula H+ 2. It consists of two hydrogen nuclei (protons), each sharing...