In organometallic chemistry, agostic interaction refers to the intramolecular interaction of a coordinatively-unsaturated transition metal with an appropriately...

in for example silanes, hydrocarbons, and dihydrogen (see also: Agostic interaction). In complexes of non-innocent ligands, the ligand is bonded to metals...

particularly common subset of sigma complexes are those featuring an agostic interaction where a C–H σ-bond on one of its ligands 'leans' towards and interacts...

bonding also includes many kinds of interactions, including σ-bonding, π-bonding, metal-to-metal bonding, agostic interactions, bent bonds, three-center two-electron...

iodide. Some metal alkyls feature agostic interactions between a C-H bond on the alkyl group and the metal. Such interactions are especially common for complexes...

been seen forming a coordination to lead in [2,4,6-(CF3)3C6H2]2Pb. Agostic interactions have also been shown to stabilize plumbylenes. DFT computations on...

tetrahedron. Each methanide in the tetramer in methyllithium can have agostic interaction with lithium cations in adjacent tetramers. Ethyllithium and tert-butyllithium...

W(CO)3(P-i-Pr3)2(H2). In such cases, the unsaturated complex in fact features an agostic interaction that is displaced by the H2. In other cases, H2 will displace anionic...

further inter-cluster agostic interactions. In contrast the bulkier cluster (tertiary-butylLi)4, where intercluster interactions are precluded by steric...

ISSN 0001-4842. Brookhart, M.; Green, M. L. H.; Parkin, G. (2007). "Agostic interactions in transition metal compounds". Proceedings of the National Academy...