Silylation is the introduction of one or more (usually) substituted silyl groups (R3Si) to a molecule. Silylations are core methods for production of organosilicon...

trifluoromethanesulfonic acid. It is commonly used as a Lewis acid catalyst, e.g. in silylations. A white powder, zinc triflate is commercially available, though some...

laboratory glassware, making the surfaces more lipophilic. By the process of silylation, polar functional groups such as alcohols and amines readily undergo reaction...

Volumes, vol. 8, p. 616. Kuwajima, I.; Nakamura, E.; Hashimoto, K. (1990). "Silylation of Ketones with Ethyl Trimethylsilacetate: (Z)-3-Trimethylsiloxy-2-Pentene"...

rn01923. ISBN 9780470842898. Stalling DL, Gehrke CW, Zumwalt RW. A new silylation reagent for amino acids bis(trimethylsilyl)trifluoroacetamide (BSTFA)...

organosilicon compounds is found to be very efficient and replaced TMSCl reagent. Silylation of glutamic acid with excess hexamethyldisilazane and catalytic TMSCl...

which all have an abundance of hydroxyl groups. Silanization differs from silylation, which usually refers to attachment of organosilicon groups to molecular...

deprotection methods are too harsh for the substrate. The mechanism involves silylation of the carbonyl oxygen and elimination of tert-butyl iodide (1), methanolysis...

Kerry N. Betz, Alexey Fedorov, Brian Stoltz, Robert H. Grubbs (2015). "Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst"...

chloride. Related to its tendency to hydrolyze, TMSOTf is effective for silylation of alcohols: (CH3)3SiO3SCF3 + ROH + Et3N → ROSi(CH3)3Si + [Et3NH]O3SCF3...