Silylation is the introduction of one or more (usually) substituted silyl groups (R3Si) to a molecule. Silylations are core methods for production of organosilicon...
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trifluoromethanesulfonic acid. It is commonly used as a Lewis acid catalyst, e.g. in silylations. A white powder, zinc triflate is commercially available, though some...
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laboratory glassware, making the surfaces more lipophilic. By the process of silylation, polar functional groups such as alcohols and amines readily undergo reaction...
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Volumes, vol. 8, p. 616. Kuwajima, I.; Nakamura, E.; Hashimoto, K. (1990). "Silylation of Ketones with Ethyl Trimethylsilacetate: (Z)-3-Trimethylsiloxy-2-Pentene"...
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rn01923. ISBN 9780470842898. Stalling DL, Gehrke CW, Zumwalt RW. A new silylation reagent for amino acids bis(trimethylsilyl)trifluoroacetamide (BSTFA)...
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organosilicon compounds is found to be very efficient and replaced TMSCl reagent. Silylation of glutamic acid with excess hexamethyldisilazane and catalytic TMSCl...
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which all have an abundance of hydroxyl groups. Silanization differs from silylation, which usually refers to attachment of organosilicon groups to molecular...
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deprotection methods are too harsh for the substrate. The mechanism involves silylation of the carbonyl oxygen and elimination of tert-butyl iodide (1), methanolysis...
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as a result; thus, the development of a one-pot, one-step method for silylation and nucleoside synthesis represented a significant advance. The combination...
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Kerry N. Betz, Alexey Fedorov, Brian Stoltz, Robert H. Grubbs (2015). "Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst"...
8 KB (692 words) - 23:40, 10 December 2023